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Many different
corrosion mechanisms exist. The most common types are generally well
understood. For each, the process is complex, incorporates many factors, and
varies according to metal and specific operating conditions. Yet all still
remain difficult to control, and represent a very serious threat to most piping
systems. Once established, most corrosion problems will produce future years of
operating difficulty and expense at varying levels of severity.

A quick review of
the six forms of corrosion commonly found at HVAC and process cooling piping
systems is often helpful in understanding their end result. They are:
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Generalized corrosion is the well distributed and low level
attack against the entire metal surface with little or no localized
penetration. It is the least damaging of all forms of corrosion. Generalized
corrosion usually occurs in environments in which the corrosion rate is
inherently low or well controlled - such as for chemically treated closed
circulating systems, and in some open water systems.
It is the only form
of corrosion whereby weight loss or metal loss data from corrosion coupons or
ultrasonic testing can be used to accurately and reliably estimate corrosion
rates and future pipe life expectancy.
View a photo gallery
of various corrosion types.

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Often termed "under deposit corrosion," this is a localized,
deep penetration of the metal surface with little general corrosion in the
surrounding area. Due to surface deposits, electrical imbalance or some other
initiating mechanism, all existing corrosion potential attacks a select number
of individual sites.
In most cases, pitting is extended throughout the
entire metal surface, creating an irregular or very rough surface profile. In
other instances, pits are concentrated in specific areas, leaving the majority
of the metal surface in like new condition.
Pitting is the most common
form of corrosion found where there are incomplete chemical protective films,
and insulating or barrier deposits of dirt, iron oxide, organic, and other
foreign substances at the pipe surface. It is prevalent at galvanized steel
pipe, where any failure of the galvanizing invokes a pitting condition. Pitting
corrosion may include: crevice corrosion, water-line attack, under deposit
attack, impingement or erosion corrosion attack, and concentration-cell
corrosion.

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This is an aggressive and localized
form of corrosion due to the electrochemical reaction often found between two
or more dissimilar metals in an electrically conductive environment. It occurs
because the more electronegative material (the anode) is attacked by the more
electropositive material (the cathode).
The most common example of such
corrosion activity, widely found throughout HVAC and process plant operations,
is the direct connection of brass valves to carbon steel pipe, or between
copper tubing and steel pipe - where the steel serves as the anode, and the
brass or copper the cathode. Carbon steel pipe, without the protection of a
galvanic insulator, will show the highest rate of corrosion under such
conditions - usually developing over many years.
The severity of pipe
loss due to galvanic activity is often found relative to the general corrosion
activity of the piping system itself - with little or no galvanic activity
found where extremely low general corrosion rates exist. Under conditions of
high corrosion rate activity, galvanic losses often become aggressive - making
an existing pipe corrosion problem significantly worse at the threads - its
already most weakened area.
While galvanic corrosion is generally
assumed to involve only dissimilar metals, millivolt potentials can actually be
measured between similar metals under certain conditions. New steel pipe
installed during a repair or renovation is often more electronegative than
older existing pipe, and therefore may suffer from some degree of galvanic
attack. View a photo gallery
of galvanic corrosion examples.

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Microbiologically Influenced Corrosion
(MIC) is, by far, the most severe and threatening form of corrosion to HVAC
piping systems. Corrosion rates of 100 MPY have been documented. MIC is caused
by the presence of various microbiological agents under specific environmental
conditions - in some cases resulting in advanced and widespread failure of
entire piping systems within a few years.
An MIC presence usually
signals a very severe threat to the entire system - requiring extensive
cleaning and sterilization at great expense. For many affected systems, MIC
cannot be eliminated, and an elevated corrosion and pitting condition will
exist for the remainder of system life.
MIC produces large and deep pits
due to the microorganism's utilization of iron as an energy source (often as an
alternative to oxygen), and through the production of strongly corrosive
metabolic by-products such as sulfuric acid - which further assists the
microorganism in dissolving pipe metal. MIC exists to varying degrees of
severity, and is not exclusive to carbon steel piping systems or open condenser
water systems.
MIC is less commonly found in closed chill water piping,
in hot water heating and domestic water systems, and has been documented to
destroy copper, brass, and stainless steel pipe.
See Technical Bulletin
# C-5 for more about the threat of MIC.

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This is the gradual and selective
deterioration of a metal surface due to mechanical wear and abrasion. It is
attributed to entrained air bubbles, suspended matter and particulates under a
flow rate of sufficient velocity.
Erosion is similar to impingement
attack, and is primarily found at elbows and tees, or in those area where the
water sharply changes direction. Softer metals such as copper and brass are
inherently more susceptible to erosion corrosion than steel.
High
pressure steam will often contribute to the erosion of carbon steel. Though
typically not a problem at the water velocities encountered within most HVAC
piping systems, high corrosion rates and the entrainment of high volumes iron
oxide particulates can produce an erosion condition under certain conditions.
Erosion at the base of elbows or after multiple sharp turns of the pipe has
been documented to occur.

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Known as Corrosion Under Insulation,
CUI is a significant threat to any piping system or holding tank which operates
at lower temperatures in humid environments. In the absence of an effective
moisture barrier and a protective metal coating, any available moisture will
penetrate commonly used fiberglass or foam insulation to condense at the cold
metal surface.
Often, moisture can accumulate sufficiently to waterlog
the insulation and cause its total deterioration. This effectively creates an
untreated water condition at the outer pipe surface, and produces a corrosion
problem on two fronts.
In outdoor environments, moisture, rain, snow,
and ice can also penetrate the insulation due to physical damage, wear, or by
the failure to install sealants at the overlap of the hard metal outer shell.
CUI is commonly found at cold water domestic piping, free cooling
condenser water systems, and especially at chill water piping - being most
severe at the colder supply side piping. The degree of CUI type corrosion
depends upon a combination of pipe temperature, insulation thickness, vapor
barrier, and humidity.
In extreme examples of high humidity, CUI
corrosion will even occur on typically warm condenser water piping. Conversely,
the extremely cold temperatures of a brine or ammonia refrigeration plant can
create substantial exterior pitting even from a relatively dry
atmosphere.
CUI corrosion usually remains hidden until severe damage has
occurred to the pipe, producing telltale discoloration at the insulation
itself, or failure. In many cases, CUI corrosion can exceed the degree of
physical damage caused by internal corrosion of poorly treated open condenser
or process cooling water piping.
View a photo gallery
of under insulation corrosion examples. |
Of the above
mentioned corrosion conditions, microbiological MIC, under deposit pitting, and
galvanic corrosion are, by far, the most damaging corrosion types, since they
localize their aggressive action against the pipe metal at one or a few
specific points to produce extremely high wall losses and failure. They are
also the most difficult to resolve. Access other Internet
sites offering valuable information on corrosion issues.

CorrView
International offers a series of photo galleries taken from 10 years of past
ultrasonic piping investigations. A review of the different types of corrosion
is often helpful in initially determining the likely corrosion cause. In many
cases, however, a combination of conditions will exist within the same system -
therefore requiring sufficient monitoring over enough locations to provide a
reliable corrosion rate assessment.
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Whereas
controlled generalized corrosion may take many decades to produce even minor
operating problems, aggressive and localized corrosion, such as under deposit
and MIC, can accelerate the need for pipe replacement to as little as a few
years - sometimes with little noticeable indication that such a problem exists.
A pitting condition is often suggested by measured corrosion rates exceeding 5
MPY, or a highest to lowest wall thickness variation of over 0.050 in., and
should be addressed immediately.
It
should be noted that some mechanical, engineering design and age related
factors can also produce or contribute to failures similar to those caused by a
high corrosion or pitting rate alone. Therefore, various investigative tools
may be need in order to correctly identify a piping failure problem.
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