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In order to
retard the deterioration of the highly corrosion susceptible carbon steel pipe
commonly specified for HVAC systems and process cooling waters, chemical water
treatment programs of varying degrees of complexity and effectiveness are
maintained. The present condition of any facility is therefore greatly
dependant upon not only the current water treatment contractor, but on the
actions or inactions of all others beginning from the time the piping was first
installed, and possibly before.
While
typically receiving blame for all corrosion problems, system condition is not
totally dependent upon the water treatment contractor alone - with operator
actions, proper maintenance, environmental issues, budgetary limits, equipment,
controls, and engineerging and design issues often playing critical
roles.
A successful and well maintained
chemical water treatment program will hopefully minimize general corrosion
activity to within an acceptable level - thereby eliminating any threat to the
piping infrastructure. It should also minimize any secondary effects, such as
under deposit pitting caused by a buildup of corrosion product and MIC.
Ideally, the annual measured loss of metal for any piping system will be far
less than the tolerable mil per year (MPY) corrosion limit calculated for the
life expectancy of the system.

Just how much the
corrosion rate impacts a piping system can be easily estimated. For example,
the service life of a 12 in. diameter schedule 40 open condenser water system
operating at 150 PSI will be the difference between its minimum acceptable wall
thickness dimension of 0.175 in. (typically), and its original wall thickness
of 0.406 in.
At a low rate of 1 mil per
year (MPY), the life expectancy of such a piping system is easily 200 years, or
virtually limitless. However, at 12 MPY, and under the high pitting conditions
which would accompany such elevated corrosion activity, its useful life is
dramatically reduced to only 19 years or less - a significant and intolerable
loss of service to any building or plant operation.
See Technical Bulletin
C-1 regarding the pounds of steel pipe lost at different corrosion
rates.
For most typical HVAC or
process cooling waters, the corrosion activity of a condenser or open water
system will exist somewhere between such high and low corrosion limits. Unlike
low corrosion rates which tend to remain uniform over decades, however, high
corrosion conditions generally tend to worsen at an accelerating rate if not
quickly and effectively addressed.
While
corrosion rates will vary depending upon the type of piping system involved,
its material of composition, and chemical water treatment effectiveness, there
are some established guidelines to follow.

In general, an
open water carbon steel corrosion rate of 1 MPY or below is considered
excellent, 2-3 MPY is considered good, and a rate of 4 MPY is borderline
acceptable. Corrosion rates at or exceeding 5 MPY warrant immediate
investigation. Rates of 10 MPY and greater signal a serious threat to system
safety, reliability, and building or plant operations.
Any corrosion rate above 15 MPY generally
indicates a severe pitting condition, an under deposit or cell corrosion
condition, or possibly MIC. In most cases, such high corrosion rates
dramatically reduce service life, and strongly raise the probability of a
premature piping failure. Corrosion rates above 25 MPY are not uncommon where
under deposit corrosion and MIC are
involved.
Closed system corrosion rates
are considerably lower, and are far more easily maintained due to the lesser
external influences on the system. They are also treated at much higher
chemical concentrations. Corrosion activity against a typical closed steel
piping system should never exceed 1-2 MPY, and can often be maintained to half
that amount with only minimum attention and expense.
See Technical Bulletin
# M-12 regarding why closed and open piping systems are treated to different
chemical concentrations.
Our
experience has shown that a good water treatment program, well applied and
rigidly maintained, along with some additional preventative actions such as
full flow or side stream filtration, regular chemical cleanings and
sterilizations, and a supplemental chemical dispersant, will achieve excellent
corrosion control in most cases. In many examples, however, the currently
achieved corrosion rate is dependant upon all previously applied chemical
treatment programs, their effectiveness, and the interior pipe wall conditions
they have produced.
Where extremely low
corrosion rates are reported of less than 0.5 MPY for steel piping, suspicions
should be raised toward the method of testing employed, and of whether
representative samples have been taken, or the correct procedures used. This is
especially true for open water systems - those most often employing corrosion
coupon testing.
The under reporting of
corrosion rate by corrosion coupons is a common occurrence due to a large
variety of factors. Read more about the
many limitations of corrosion coupons. Questions regarding a
questionable corrosion rate determination can often be resolved using
ultrasonic testing or metallurgical investigation.

Due to the
awareness that corrosion always exists to a certain degree, it is assumed that
consulting engineers, building operators, and mechanical contractors have
accounted for this annual loss of wall thickness in their original equipment
and piping design. Our experience in testing hundreds of such systems, however,
shows this may not always be the case.
The significantly higher corrosion rates
typically found today at open cooling systems suggest placing far greater
emphasis on methods to control corrosion. It also suggests to better prepare
for those installations where, for whatever reason, corrosion control may not
be adequate. While higher corrosion rates would suggest the interest to install
heavier piping schedules, we have actually found the opposite - with thinner
schedule 20 and schedule 10 stock now commonly recommended as cost cutting
alternatives. Access other Internet
sites offering valuable information on corrosion issues.

For some piping
systems, such as galvanized steel, copper, or brass pipe carrying domestic
water, steam supply and steam condensate systems, gas or oil lines, etc., the
chemical inhibition of corrosion is not available, not permitted, or not
desired - thereby making the corrosion of such systems entirely dependant upon
water chemistry and corrosivity, environmental factors, metal quality, coatings
or barrier protection, and design engineering. Close monitoring of such piping
systems can therefore rate an even higher priority.
Brass, copper, and other non-ferrous
metals also suffer from specific types of metal loss such as dealloying or
dezincification - whereby the selective removal of one component of the metal
may take place over extended time, and eventually leading to its embrittlement,
cracking, and failure. Microbiological attack is also always a serious concern.
In such cases, metallurgical analysis is usually required in order to identify
the cause.

Ultimately, the
quality of the water treatment receives either the credit or blame for the
internal condition of any piping system. While additional factors exist to
influence the condition of any piping system, some general recommendations
toward providing an effective corrosion control program are presented
below:
- Maintain a
strict water treatment program from a reliable vendor. Avoid low bidding as the
sole criteria for awarding contracts.
- Automate all
chemical feeds and blowdown. Chemical inhibitor feed should be based upon water
meter makeup, biocide feed based upon an alternating timer, and blowdown based
upon water conductivity.
- Install a side
stream filtration to reduce overall particulates - a significant and well
documented cause of all corrosion problems. Filtering even 10% of the flow rate
will greatly help in reducing the buildup of dirt and debris. A wide variety of
manual and automatic filters are available. Full flow filtration is always
preferred, and is far more important for open circulating systems.
Review Technical
Bulletin W-4 for a comparison of different filter
types.
- Review all test
reports carefully and question any changes in
result.
- Chemically
clean and sterilize all open water systems twice per operating
season.
- Chemically
clean and sterilize all closed systems every three to five
years.
- Consider
employing an outside consultant to review the water treatment program on a
regular basis.
- Perform
independent chemical and corrosion testing through an outside
laboratory.
- Clean and flush
the cooling tower basins regularly. Corner or low flow areas are especially
susceptible to particulate settlement, and for the potential of MIC or under
deposit corrosion to develop. Cover or shield all distribution pans and basins
from the sun in order to minimize biological
growths.
- Incorporate a
supplemental chemical dispersing agent into the water treatment program.
Combined with filtration, this will help prevent the settlement of
particulates, and redistribute settled material for gradual
removal.
- Perform regular
corrosion coupon testing. While their under reporting of true corrosion rate
activity is a common concern, coupons well document the presence and general
effectiveness of an inhibitor, as well as allow trending of relative corrosion
activity.
- Install
multiple "spool pieces," or test sections of pipe which can be periodically
removed for visual and metallurgical examination and returned to service. Spool
pieces are ideal for evaluating the effectiveness of any deposit cleaning
program.
- Include monthly
testing for biological cell counts in the water treatment program. Biological
contamination can develop within a few days period of time under favorable
conditions. Currently used non-toxic inhibitors, and their regulated dosages,
place an added emphasis on the effectiveness of
biocides.
- If possible,
prevent the buildup of dirt and debris by eliminating low flow areas. This is
especially common in secondary water lines having long horizontal runs. Some
studies have shown low flow conditions to reduce the effectiveness of water
treatment inhibitors as well as allowing dirt to deposit. Booster pumps or
by-pass lines are two viable and easy options to increase flow
rate.

For many property
owners and operators, just the existence of a chemical water treatment contract
is assumed to mean the elimination of that area of concern. In reality, there
are far more steps required in order to ensure a trouble free operating system.
Following 10 years of ultrasonically
testing hundreds of commercial and industrial properties, CorrView
International has well documented the failure of such logic. Even the most
effective and rigidly maintained chemical inhibitor program, provided by the
most reputable water treatment contractor, still requires additional steps by
the building or plant operators in order to provide the best corrosion
protection possible. |
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