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Over the past 10
years, CorrView International has performed numerous ultrasonic investigations
of either very old pipe installed in the early 1900's, or at properties where a
combination of old and new pipe exist. We have found our test results a
remarkable demonstration of how environmental concerns and government
restrictions, combined with less tolerant engineering practices and cost
cutting, have greatly reduced the life expectancy of most new piping
installations.

First and foremost is the obvious
superiority in quality and corrosion resistance of pre World War II pipe to
that manufactured today - whether foreign or domestic. Our ultrasonic testing
of steam systems from 1911 have shown a minimal loss of only perhaps 20% from
the original wall thickness. Testing of some galvanized steel domestic water
risers from 1920 have documented little if any wall loss and no loss of the
zinc coating.
We have certified 80 year
old steam condensate pipe, which traditionally suffers from the acidic
conditions of condensate requiring frequent replacement, as useful for another
50 years of service. Condenser water systems from the early 1940's have been
documented to corrode at below 1 mil per year (MPY) and offer hundreds of years
of future service - even at building locations where chemical treatment was
poor or non-existent.
In contrast, we find
few new properties able to control corrosion to below 5 MPY today without
expending extraordinary cost, supplemental filtration, close monitoring, and
added physical effort. Chemical treatment programs costing $10,000 only 15
years ago now reach almost 10 times that expense. Fully automatic chemical feed
and bleed systems are no loner a convenience, but mandatory. Yet, ultrasonic
and metallurgical testing at newer installations typical reveals corrosion
rates in the 3 - 5 MPY range, with some examples exceeding 15 to 20 MPY. This
even in examples where the chemical water treatment has been extremely well
maintained.
We have either directly seen
or have been advised of condenser water or process piping systems which have
been entirely replaced after only 10 years of service or less, and have found
large diameter 8 in. and 12 in. main risers repaired throughout their
facilities using emergency pipe
clamps.
Wrought iron ASTM A 72 pipe, which
is well recognized and documented to provide extremely long life due to its
internal grain structure and inherently high corrosion resistance, can be found
at many older pre-1970 properties. However, it was removed from U.S. production
in 1968 and is no longer available.
In
cases where we have investigated building properties having both new carbon
steel and older wrought iron pipe, we have consistently provided remaining
service life estimates in the hundreds of years for the wrought iron, as
opposed to a few decades or less for the newly installed carbon steel. In many
examples, we have found unpainted and un-insulated wrought iron pipe surviving
50 or more years of outdoor weathering with only a fine layer of surface rust
and the original ASTM markings still intact.
The use of more
expensive copper in smaller diameter distribution HVAC piping and process loops
has become the standard practice today in the effort to avoid the damaging
effects of corrosion against carbon steel. Larger diameter 8 in. and 12 in.
condenser water piping systems running the entire height of large commercial
office buildings have been entirely replaced using extra heavy copper and even
304 or 314 stainless steel - such extraordinary expense expended solely in the
effort to avoid the destructive effects of corrosion rarely seen decades
earlier.
While low cost foreign produced
pipe from Japan, Korea, Mexico, South America, and Eastern Europe has
traditionally shown the greatest susceptibility to corrosion, we have not found
recently produced American carbon steel pipe products of significantly higher
quality in terms of corrosion resistance. Aside from the obvious net effects of
stringent U.S. environmental controls and government over-regulation, as well
as the competition of low cost foreign steel, we have not been able to
establish suitable explanation for the obvious difference in new vs. old
American pipe products. Other changing factors acting against steel pipe
produced today obviously exist.
For those many
reasons, CorrView International strongly recommends that a higher corrosion
rate should be anticipated regardless of any corrosion control measures planned
or implemented. It should be noted that standardized corrosivity tests,
laboratory methods capable of measuring the susceptibility of a metal to a
typical corrosive environment and rating that metal according to an established
numerical scale, are available, and offer an excellent prediction or warning of
potential corrosion problems. Please contact CVI for
further information about this evaluation service.

As mentioned, in
response to such observed increases in corrosion, many property managers,
operating engineers, and plant managers have turned to the use of Type L copper
tubing (commonly called pipe) for all smaller diameter run-out distribution
lines, and in some cases even for the main risers. This, however, may only be a
short term solution to the often more complex corrosion condition, and in some
cases may actually complicate an existing corrosion problem with additional and
unseen threats.
Important to consider in
the substitution of copper pipe for carbon steel is the significant difference
in initial wall thickness. Standard Type L B 88 copper for 3 in. diameter pipe
has a standard wall thickness of only 0.090 in., whereas 3 in. A 53 schedule 40
carbon steel has a wall thickness of 0.216 in. Compared to steel pipe having a
stress efficiency (a strength rating, not pressure rating) of 15,000 lb./sq.
in., B 88 copper pipe only offers 6,000 lb./sq. in. - a physical decrease in
strength of 60%. Copper pipe has less than half the tensile strength of steel,
and quickly loses that strength at high temperatures.
It is generally recognized that the
minimum acceptable wall thickness for copper tubing, under any conditions, is
approximately 0.025 in. At higher pressures, this minimum value increases -
thereby allowing for less physical wall loss to occur before being judged as
unsuitable for further reliable service. Copper pipe, since it exhibits far
less physical strength than steel, will fail sooner than steel at the same wall
thickness dimension and under the same internal pressure - making it obvious
that the greatest threat for any copper piping or components installed in a
high rise property exists at the higher operating pressures of the lower
floors.
While the corrosion rate against
copper is commonly believed to exist well below 0.5 MPY under all conditions,
CVI has well documented that the same corrosive environment responsible for
raising corrosion rates against carbon steel past 10 MPY, will greatly increase
the copper corrosion rate above its normal value as well.
In many of our previous ultrasonic
examinations of condenser water systems which have shown a high corrosion rate
against carbon steel, we have also measured elevated corrosion attack against
the copper pipe. In fact, it is not uncommon to identify condenser water
systems having both a high steel corrosion rate of 15 MPY and a corrosion rate
against copper at 5 MPY or more.
Having a
5 MPY copper corrosion rate aggressively working against piping which may only
have an available 30 mils to 60 mils (0.030 in. to 0.060 in.) of wall thickness
over minimum acceptable standards translates to a system which will reach those
minimum standards in only a few years. Copper therefore should not be relied
upon or viewed as any form of safe or corrosion immune alternative given
conditions where a high carbon steel corrosion rate has already been
documented, or where a high copper corrosion rate is suspected.

For older
pre-1970's building properties or plant operations, it is unlikely to find
anything but schedule 80 or extra heavy black pipe in use for cooling water,
steam, or steam condensate service. However, today, schedule 40 is the standard
specified. Contrasted to a 0.322 in. wall thickness for an 8 in. section of
schedule 40 pipe, schedule 80 provides a significantly greater 0.500 in. of
available steel; for larger diameter standard grade pipe of 0.375 in. wall
thickness, extra heavy again offers 0.500 in. thickness.
See our table of pipe
sizes and schedules.
With
internal operating pressures rarely a deciding factor on pipe selection within
the commercial building and process cooling market, the previous use of heavier
materials, we believe, has been more intended to counteract the known effects
of corrosion activity and thereby provide longer service life.
It is important to realize that decades
ago, design engineering for piping systems assumed a reasonable and readily
achieved 1 MPY corrosion rate over an intended life expectancy of about 65
years for the typical building property - therefore a theoretical 65 mil
corrosion rate or "corrosion factor" was typically applied in piping
calculations for open condenser water or process cooling applications.
In other words, consulting and design
engineers estimated a total loss of only 65 mils of pipe over the assumed
lifetime of the property. Any additional pipe wall thickness exceeding the
corrosion factor and that needed to contain the internal pressure and stresses
was simply extra insurance against corrosion losses and future operating
problems.
Today, it is not unusual to
measure the same loss of 65 mils after only 5 to 10 years of service, and
sometimes in as little as two years. But while corrosion activity has obviously
increased, the response to this greater loss of pipe has not been factored into
the design and planning of modern piping systems - leaving very little if any
tolerance for a system wide corrosion rate exceeding a few mils per year.
CorrView International has found many
building properties constructed in the 1970's and before having clearly
benefitted by such engineering decisions - with the heavier schedule 80 pipe
wearing over those many decades to approximately schedule 40 today. Some older
properties, due to the original use of better quality schedule 80 steel,
actually have heavier and longer lasting pipe than their newly constructed
neighbors. It is an amazing paradox we have well documented in endless
ultrasonic testing investigations.
This
change in engineering design toward using thinner schedule 40 pipe, and
sometimes schedule 20 and schedule 10, is far more obvious and threatening for
smaller diameter threaded applications - where the additional loss of metal
during the threading process often reduces the life expectancy of open
condenser water or process water piping to a decade or less. Threading
typically reduces the available wall thickness by over 50% - leaving a 0.154
in. thick piece of 2 in. schedule 40 pipe, less its thread cut of 0.087 in.,
with a true available and working wall thickness of only 0.067 in. beginning at
day one. See our table of
thread loss for different size
pipe.
For piping systems having
a typical 5 MPY corrosion rate, total penetration of the threads will occur
within 13 years of installation - guaranteed. In reality, failure usually
occurs years earlier. In fact, the use of schedule 40 or standard grade pipe in
threaded open water condenser applications does not even meet minimum
acceptable engineering guidelines for new piping systems, and will typically
provide only 10-15 years of service life under good to moderate corrosion
conditions. The failure of a threaded schedule 40 piping system in under 5
years is not unusual, based upon our
experience.
A growing concern is the
recent increase in the use of grooved and clamped constructed schedule 10 pipe
in fire sprinkler service. While providing adequate wall thickness initially,
schedule 10 pipe has approximately half of the thickness of schedule 40,
leaving virtually no tolerance for corrosion to occur. Where the pipe is filled
and left stagnant over extended time, a small amount of corrosion takes place,
oxygen is depleted, and the corrosion process virtually stops. However, where
the system is frequently drained, or where service extensions, leaks, or
repairs bring in fresh water, corrosion rates can reach the level of open water
systems, and premature failure is
inevitable.
Clamped schedule 10 pipe is
seeing greater use in open condenser water piping systems as well - producing
disastrous results in even less time.
CVI
overwhelmingly recommends using heavier schedule 80 steel pipe in all small
diameter applications calling for threaded joints. We also recommend using no
thinner than schedule 40 pipe for fire sprinkler or open water condenser
systems - whether using threaded, welded, or Victaulic or grooved clamped
construction.

For decades,
building and plant engineers relied solely upon the use of chromate based
chemical additives to provide the required corrosion protection of steel piping
systems. With even the most inferior application methods, often nothing more
than an unmeasured scoop of chromate powder dumped into the cooling tower sump
at irregular intervals, corrosion rates could often be maintained at or below 1
MPY. Biological fouling was a rarely encountered problem due to chromate's
inherent toxicity. Such trouble free operation ended, however, in the
mid-1980's - with the prohibition of all hexavalent chromate use in open water
circulating systems in the United
States.
Today, molybdate, phosphate, and
other U.S. EPA approved chemical inhibitors rarely equal the effectiveness of
past chromate treatments. Though offering impressive corrosion suppression in
bench test or laboratory settings, non-chromate programs rarely provide similar
results under real world conditions. They are documented as being substantially
ineffective in stagnant, low flow, or dead ended piping areas. During our years
of ultrasonic pipe testing, we have identified numerous examples where the
highest corrosion rates have been found exclusively at those areas having the
lowest flows.
Non-chromate treatments
offer no microbiological or fungal control - thereby placing increased emphasis
on the use of alternating biocide chemicals. Unfortunately, biocides themselves
have had their effective half-life reduced to approximately 6 hours by U.S.
federal and state environmental authorities. The result - a legal limit of the
amount of biocide one can apply over a given period of time, as well as a legal
limitation over its strength, effectiveness, and the time it will remain
active.
And yet, microbiological activity
has been found to play an increasing role in metal corrosion - MIC being the
most serious piping threat known. The alternative, using oxidizing biocides
such as chlorine, bromine and ozone, all offer excellent microbiological
control at the trade off of greatly increased corrosion and pitting. The common
overuse of oxidizing agents such as chlorine and bromine on a weekly or daily
basis have been known to produce severe pitting of steel and copper pipe, and
to quickly remove the galvanizing coating from cooling tower pan surfaces.

Together, the
combination of all the above named factors has placed a higher priority on
corrosion control which did not exist 20 years ago, and which has raised the
issue of chemical treatment, and the monitoring over its effectiveness, to new
levels of importance within those involved in building and plant engineering,
maintenance, and operations.
Virtually
all advanced piping failures we have seen have been traced back to an
ineffective or lacking water treatment program at some point in the building's
history - most notably due to poor initial cleanout and start-up procedures.
Quite clearly, the first six months of operation are critical, and can mean the
difference between long and reliable operation, or substantially fewer years of
corrosion inflicted problems.
To the
inherent limitations of the chemicals must be added the experience and
reputation of the water treatment professional. A lack of knowledge,
experience, and professionalism, or a primary interest for profits can be
equally as damaging to a piping system as a lack of chemical protection
entirely.
A less reputable water
treatment company may be discovered and replaced, but the effects of even six
months of sub-standard service can initiate a lifetime of corrosion troubles
for an office building or plant operation. A further limitation may also be the
budget constraints of the property or plant itself, or the need to meet a
contract limit established by a previous water treatment vendor. The failure to
timely recognize or effectively address a corrosion problem will place even
further demand upon any chemical treatment contractor and available control
products.
Ultimately, some building
property or plant operator is faced with with not only the difficult task of
correcting or replacing a piping system, but perhaps a responsibility for the
actions or inactions of those years prior as well. Constant and accurate
corrosion monitoring is therefore they key. |
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