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It is a generally
recognized fact that fully drained or partially drained piping systems are far
more susceptible to corrosion than those containing treated water, or even
untreated water. Given a moist environment in combination with the presence of
abundant air and oxygen, exposed piping has been documented to corrode at a
rate two to ten times that of other water filled pipe of the same type, and
located within the same circulating system. Condenser or open water systems
clearly suffer the greatest.
In cases
where condenser water piping is drained down within the interior of a building
to protect it from freezing, it is common to measure significantly higher
corrosion rates at the rooftop or outside level. In those cases, roof level
piping will require replacement many decades before the remainder of the
system. The buckets of iron oxide and scale typically removed from strainers,
condenser heads, and heat exchanger tubes at every spring start-up are
partially the result of such higher off-season corrosion activity.

Ironically,
corrosion coupon racks, typically the only form of corrosion monitoring used,
cannot be employed at drained down pipe due to a lack of water flow. They are
rarely installed in outdoor or roof level locations, but if present, are
generally removed during the off-season. Read more about the
limitations of corrosion
coupons.
Of course, corrosion
at the outer surface of the exposed rooftop pipe will also occur if not
properly coated, insulated, and protected - a maintenance problem often
identified as a contributing factor to an overall higher measured corrosion
rate. However, it is most often the pipe's interior, having been totally or
partially drained over many years, which places the system at greatest risk of
advanced failure.
The below comparison of
wall thickness measurements and estimated corrosion rates, taken from an actual
ultrasonic piping investigation of a New York City commercial property, clearly
illustrates the differences which, to some degree, always exists between
drained and filled piping within the same exact condenser water
system.
In this example, the left side of
the page represents test results taken from an ultrasonic evaluation of a
section of 18 in. extra heavy condenser water pipe located in the sub-basement
machine room area of a 42 story New York City office building, and never
drained of chemically treated water.
The
right side of the page represents the same exact pipe at the 30th floor outdoor
shaftway, where it has been drained every single year during its five month
winter season. The pipe is the same in all respects - having extra ASTM A 53
heavy stock with an initially specified wall thickness of 0.500 in., a solid
history of excellent water treatment maintenance, and service life of over 45
years. Descriptions of the various charts and bar graphs precede each set of
report data.

In a direct
comparison of current wall thickness measurements, test results show
significantly lower remaining pipe metal at the drained test site, shown below
to the right. Also, the greater deviation between thickness measurements at the
drained piping illustrates the much higher level of pitting activity at that
location. Please note the differing scales for wall thickness at the left side
of each graph.


The below
calculations are based upon the average of all recorded ultrasonic wall
thickness measurements illustrated above. Differences in average measured pipe
thickness, corrosion rate, and remaining pipe life life are dramatic. As shown,
the annual draining of this system has actually increased the average corrosion
rate of the roof level piping FOUR TIMES times
that of the rest of the system. As a result, the lifetime of the piping has
been reduced by nearly TEN FOLD!


The below tables
show the same basic set of calculations as in Comparison # 2, except that they
are based upon the lowest measured wall thickness value of each set.
Such data represents a weak link or worst case scenario, and offers an estimate
of when the most aggressive corrosion activity will deteriorate the piping past
its safe recommended limit.
Shown below,
differences in corrosion rate, percentage of loss, and retirement date are even
more pronounced. In fact, the minimum wall thickness of the constantly filled
pipe significantly exceeds the standard specifications of any new pipe
installed today, while the upper pipe exists at nearly half that value.


While the
original pipe wall thickness and minimum allowable thickness values remain
constant for both test locations, a major difference is obvious in the amount
of pipe remaining. For the subject property, ultrasonic testing indicated that
the minimum measured pipe wall thickness of the drained piping is nearing its
minimum allowable safe operating limit. Yet the water filled pipe offers almost
unlimited remaining service.


The below graph
is based upon data taken from a separate ultrasonic investigation of a 37 floor
condenser water piping system at a downtown New York City office building. The
blue line represents the average corrosion rate based upon all wall thickness
measurements; the red line represents the highest corrosion rate based upon the
lowest individual wall thickness. Since the condenser piping was installed
exposed to the elements within an outside stairway, it had been drained
completely to the bottom for the previous 39 winter
seasons.
Ultrasonic thickness testing was
performed at the roof and at each floor down to the basement. As expected,
testing showed a high corrosion and pitting condition throughout most areas.
When the test results were sorted based upon the physical floor location,
highest to lowest, we found a clear trend - with noticeably higher corrosion
and pitting activity at the upper areas of the pipe, and the only low and
uniform examples of corrosion found at the lowest 4-5 floors. As in many past
investigations of of drained vs. filled pipe, an almost 10 to 1 relationship
was shown to exist.

Although the
entire piping system was drained, the higher loss of pipe wall thickness at the
upper floors was attributed to the abundance of fresh air and oxygen migrating
through the cooling tower openings and down the risers. The lowest sections of
pipe, as expected, showed the lowest corrosion activity for the exact opposite
reason. Similar results have been found in many other CVI investigations, as
well as by other investigators. See Technical Bulletin
# P-14 for another case history of wall loss due to draining pipe over many
years.

There are
currently only four feasible ways to reduce the corrosion rate within a piping
system which is partially or fully drained over any period. One or more may
apply depending upon conditions.
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The
easiest, though least effective measure, is to greatly increase the level of
the standard chemical inhibitor just prior to draining. This theoretically
leaves a heavier coating of rust protection on the piping to provide partial
protection against oxidation while drained.
In reality, CVI has found
little benefit through this action, and most properties which do follow such
procedures generally still find an excessive corrosion loss at drained pipe
locations.
Most water treatment companies offer special lay-up
inhibitors, although it is difficult to judge their effectiveness in the
field.

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A
second and extremely effective method is to introduce a supplemental chemical
rust inhibitor specifically formulated for the purpose of preventing corrosion
during lay-up periods. Numerous formulations exist, including the newest
development of powders called Vapor Corrosion Inhibitors (VCI).
These
gas producing products place a protective and penetrating layer of corrosion
inhibitor on the the surface of the metal to provide virtually total corrosion
control for up to two years.
They require a general, though not
airtight, sealing of the piping system in order to allow the protective gas to
sublime, move from solid directly to gaseous phase, and then migrate throughout
the piping.See Technical Bulletin
# C-9 for further information on VCI corrosion
inhibitors.

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A third rarely used, but highly
effective method, is to fill the empty system with a blanket of nitrogen gas,
displacing the air and oxygen, and stopping the corrosion process almost
entirely.
This procedure requires an airtight piping system - which may
be difficult to achieve at the cooling tower end - the area most in need. It is
rarely used in HVAC applications.

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Since corrosion cannot continue
without a required level of moisture, reducing that moisture content below a
certain dew point will inevitably stop or substantially lower all corrosion
losses. Drying, however, is often difficult due to the physical configuration
of a piping system, and especially for open systems at the cooling tower
itself, which would require temporary closure.
Drying can be
accomplished by one or a combination of heating, desiccant use, or the
introduction of super dried air into the system. |

An extremely
important step prior to any lay-up procedure is to chemically clean and
sterilize the entire system. By removing unwanted rust, dirt, and biological
matter, the above inhibitor methods will work much more effectively due to the
increased amount of contact between the chemical inhibitor and base
metal.
High corrosion and pitting rates
present a significant threat to every building or plant property which drains
its piping for even short intervals. Most often, that wall loss is not
recognized until a failure occurs, or interest to learn the source of start-up
deposits is raised. It is a problem often not addressed due to a combination of
non-awareness, physical difficulty, questionable effectiveness of result, and
an expenditure benefitting only a potentially limited amount of the overall
piping system.
©
Copyright
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