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Microbiologically
Influenced Corrosion (MIC) is a problem in many commercial and industrial
properties simply due to the fact that microbiological communities are such
common inhabitants in our environment. MIC is most commonly found in open
condenser water and process cooling loops, although its presence has been
identified in most piping systems - from domestic water and fire sprinkler
lines, to those serving hot water heating
systems.
For open systems, the main entry
point for MIC is via the cooling tower - which acts similar to a giant air
scrubber by washing large quantities of particulates, organic material, and
microbes into the water. For closed systems, the microbes present in the
make-up water usually provide the initial source of the problem. Under
favorable conditions, even a small initial contamination can produce
significant end result.
MIC based
corrosion is extremely aggressive, and in its worst form, will lead to piping
failures within a short period of time. Once established, MIC is extremely
difficult to eliminate, and may elevate into a chronic maintenance and
operating problem for years following. The failure to totally remove MIC from
deep pits and the furthermost branches and dead legs of a piping system
generally results in reinfection by the same microorganisms within a short
period of time.
Most alloys including
steel, cast iron, copper, and even stainless steel are known to be susceptible
to MIC corrosion - meaning that MIC can attack any piping system given the
proper conditions. Of the many potential corrosion problems which can plague
any building or plant property, MIC is unquestionably the most feared, as well
as the most difficult to identify and correct.

When a metal
surface is exposed to water, the microorganisms typically resident in the water
quickly attach themselves to the surface to form a biofilm - which is a living
biological mass composed of bacteria, algae and other microorganisms. Those
microorganisms grow, break free, and distribute throughout the piping system.
Chemical biocides are generally applied to prevent the growth of such
microorganisms, although they are not always effective. Even under well
controlled conditions, MIC can develop within a short period of time due to a
variety of factors. Once MIC has gained a solid presence in the system, the
reliance on biocides alone as a corrective measure becomes
worthless.
Many forms of MIC types exist
to present different levels of threat. Some microorganisms are capable of
producing metal dissolving metabolic by-products such as sulfuric acid, and are
often identified within a classification termed sulfur reducing bacteria, or
SRB. Whereas normal condenser water corrosion rates may range between 1 to 5
mils per year (MPY), MIC attack often results in accelerated corrosion rates
exceeding 20 MPY and more - causing penetration of some metal surfaces in as
little as one or two years.
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Microbiological
activity should be assumed to exist to some degree in anything but a steam
piping system - an excellent indicator of which is always plate count
monitoring. Whether a microbiological presence turns into a severe corrosion
loss, however, depends upon a number of special factors related to the piping
system and service involved.
MIC can be
found in domestic cold water systems comprised of copper pipe, and will
similarly produce pinhole leaks in short periods of time. Due to the optimal
temperatures maintained in hot domestic water systems, the possibility of
encountering MIC is slightly higher - though still not a common occurrence.
While MIC is a concern due to its potential for damaging domestic water piping,
it is still of secondary importance to other pathogenic microorganisms such as
Legionella Pneumophila - which can cause acute sickness to humans, and in
isolated cases, even death.

An understanding
of any corrosion problem is an extremely important first step prior to
attempting any cleanout procedure. This requires a thorough assessment of
remaining pipe condition, and most importantly - the identification of any weak
areas of the piping system.
For most MIC
problems, the greatest threat always exists at the threaded joints, at fixtures
such as temperature wells and pressure gauges, and at lower floors where higher
pressures exist. Installing sufficient shut-off valves to isolate critically
weakened areas is well recommended in the event a chemical cleanout produces
further leaks - an always present danger. Initiating a chemical cleanout
program that results in producing an overhead lawn sprinkler system is a
nightmare no building owner or operator wants to ever be
responsible.
Corrosion coupons, ultrasound
and other nondestructive testing methods are generally ineffective at showing
an MIC condition. Therefore, a full metallurgical and biological analysis of
multiple representative samples of pipe becomes another prerequisite step.
Viable cell culture tests can determine both the types and approximate volume
of microbes present in the system. This is an extremely important tool since
the presence of specific microbes and their metabolic by-products are
indicative of MIC. For example, the presence of ferrous iron, sulfide, and low
pH at the corrosion site would support a diagnosis of SRB or sulfur reducing
MIC.
New advances in DNA technology now
allow the identification of the specific types of bacteria within a MIC
tubercular deposit and provide unquestionable proof of exactly what is causing
the problem. See Technical Bulletin
# C-8 about new DNA identification methods for microbiological
growths.

Prevention of MIC
depends on constant vigilance and awareness of the many conditions that
contribute to its formation. Deposit covered metal surfaces, low flow
conditions, interior surface pitting, high bacterial counts, the absence of (or
improperly applied) water treatment, as well as various other conditions
contribute to the growth of bacteria - thereby placing the entire system at
risk. A measured corrosion rate exceeding 10 MPY always suggests the
possibility of MIC, while a rate of over 25 MPY almost confirms
it.
A fully automated chemical feed and
bleed station is absolutely mandatory for any condenser water or open process
water system today. In addition, regular monitoring for correct inhibitor
level, biological characterization, testing for microbiological cell count,
frequent visual inspection of any pipe access points, and the use of multiple
CorrView ® corrosion monitors are all highly recommended
as a guard against MIC.
Once it has been
positively determined that a system is infected with MIC, the first decision
that must be made relates to the method of cleaning. This is an often difficult
decision which must take into account the remaining condition of the pipe wall,
physical layout of the piping system, deposit buildup, the relative level of
MIC infection, and system operating conditions, among other factors.

Resolving an MIC
problem is a matter of repeated cleanings and sterilization, followed by
testing. Generally, microbiological growths exist hidden within other deposits
in a stratification of layers. Removing only the surface deposits, therefore,
will not provide an effective solution, and it is necessary to clean the pipe
down to the bare metal if any success is expected.
See Technical Bulletin
# C-15 about an effective but rarely employed solution to many MIC
problems.
Establishing a spool
piece at a section of larger 3 in. to 6 in. pipe is well advised in order to
periodically evaluate cleanout effectiveness. Due to the high volume of rust
and particulates typically associated with an MIC problem, and the physical
volume of material returned into solution through any cleanout procedure, an
effective filtration system is always
recommended.
Following the elimination or
control of an MIC condition, added attention to the system is mandatory since
under deposit corrosion and pits will have provided the ideal environment for
new microorganisms to collect and grow. For any system which has undergone a
vigorous cleaning down to the base metal, it is imperative to increase the
inhibitor level in order to discourage new corrosion activity while the surface
metal is being passivated. Biocides should be added regularly.

Because the
microbiological agents causing MIC are generally found at the boundary layer
between the pipe and interior deposits, it is often difficult to physically
solve the problem with sterilizing chemicals alone. Increased biocide use alone
is generally useless, as they are only designed to suppress microbiological
growths, not kill and eradicate them. And the extended use of high
concentrations of strongly oxidizing chemicals such as chlorine leads to
further metal damage.
Often, a multi-stage
program of repeated heavy duty chemical cleanings and high dosage level
sterilizations must be established. The use of chemical dispersants and
chelating agents are some additional methods which may be employed to remove
the attached deposits. Mechanical cleaning using a high pressure water jet may
be applicable in some specific examples. See Technical Bulletin
# M-3 about high pressure water jet pipe
cleaning.
The benefits of any
proposed aggressive cleaning program must always be weighed against the
potential damage caused to the piping itself. Yet, it is important to realize
that the failure to aggressively address an established MIC problem will lead
to advanced pipe failure anyway! Due to the fact that MIC produces intensive
corrosion rates at localized sites, it is critically important to first
establish the extent throughout the piping system and the depth of surface
pitting prior to any cleaning program.

While the
elimination of an MIC problem is always preferred, it may not be possible for a
variety of reasons. In many cases, a severe MIC problem cannot be solved and
will be recognized as such - therefore requiring some consideration of
alternative options. Different authorities hold differing viewpoints in
addressing an MIC problem - with five generalizations presented below:
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The
preferred view, obviously, is to prevent an MIC infection from even beginning.
Attention to a strict water treatment program is critical, as well as is a
totally automated chemical feed and bleed system. Regularly performing
laboratory cultures of the water is important to verify biocide or chlorination
effectiveness. Testing for anaerobic microbes, while technically difficult, is
strongly advised in dead or low flow areas.
Periodic cleaning and
sterilization of the tower is recommended at least twice annually. Filtration
is also a plus, as it greatly reduces the particulate volume known to
contribute to any MIC growth problem.
While an indication of biological
activity can be easily determined by simple dip slides, they can not show what
may be attached and growing at the interior pipe wall surface. In such cases,
electronic biofilm monitors may offer added information.
Also quite
valuable, 3 in. or 4 in. spool pieces offer an inside look into the piping
system and provide opportunity to sample any interior deposits for
microbiological and specifically MIC analysis.

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Once established, eliminating the MIC problem altogether is the
preferred choice. Aside from being an extremely difficult task, this is often
not feasible due to the damage already caused to the piping system, and due to
the potential for any cleaning action to cause further leaks and piping
failures. Some of the largest piping failures we are aware have been caused by
acid cleanout procedures performed on weakened pipe.
In many cases,
extensive repairs must be made to the system before any cleanout is even
attempted - especially to the most vulnerable threaded pipe. This delays
greatly any remedial measures and allows even further damage to
occur.
Once any vulnerable pipe is replaced, eliminating an MIC problem
becomes an expensive exercise of repeated chemical cleaning, sterilizing and
draining the system. High pressure water jet cleaning is an excellent option in
many cases, and will remove both microbiological growths and the deposits in
one quick action.
The use of ozone to sterilize the system is another
excellent option. Although much more difficult to apply since it requires
on-site generation, ozone will effectively sterilize an MIC condition assuming
any existing deposits have been removed.

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Another view is to identify the corrosion mechanism involved and inhibit the
corrosion process to the best degree possible. Identifying a specific MIC
organism responsible is often difficult, although new developments in DNA
analysis will provide most answers.
Identifying the corrosion mechanism
is more difficult, though necessary in order to plan its remediation. By many
authoritative opinions, however, removing an MIC infection completely, once it
has been firmly established, is nearly an impossible task.
Of all
sterilizing agents, ozone likely offers the highest probability of providing a
cure for any piping system having a severe MIC condition.

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The fourth view assumes the
impossibility of eliminating MIC once present, and instead focuses on
minimizing its corrosive damage. In many cases, the higher 15-20 MPY corrosion
rates can be significantly reduced to extend system life, though random pockets
of microbiological growths may produce periodic pipe failures.
Many
corrosion and water treatment authorities consider that a piping system cannot
be returned to normal conditions once MIC has established itself system wide.
Multiple chemical sterilizations and high expense can be assumed necessary in
any such cleaning effort.

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In many cases, a piping system
seriously infected with MIC will require replacement. This occurs usually only
after MIC damage has resulted in multiple failures and the cost of another
major failure is deemed to be an unacceptable risk.
Replacing less then
the entire piping system, without good reason to believe that any MIC infection
in those remaining areas has been eradicated, will generally reintroduce the
microbiological agent into the new piping and begin the problem all over.
Intense chemical treatment and monitoring may reduce such a threat to any new
piping installed. |
In short, our
obvious recommendation is to take the necessary precautions now to ensure that
an MIC condition does not begin in the first place. Aside from operating
problems and equipment damage, an MIC infection is an extremely costly -
producing expenses from pipe testing, lab tests, maintenance overtime,
chemicals cleanings, and monitoring and services, etc. in the hundreds of
thousands of dollars.
©
Copyright
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