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Our extensive
volume of work in the field of ultrasonic pipe testing has well documented the
accuracy and reliability of this testing process, as well as its ability to
provide more valuable information than any other pipe testing method typically
employed. Combined with proper data analysis, and given sufficient test points,
ultrasonic testing (UT) provides an excellent overall evaluation of pipe wall
loss, corrosion rate, and remaining service life.
See Technical Bulletin
P-7 regarding ultrasonic pipe
testing.
A frequent conflict
exists, however, when comparing corrosion rates from new metal coupons against
corrosion rates estimated from actual wall loss measurements. In virtually all
cases, reported corrosion coupon rates will exist far below those calculated
based upon actual wall thickness loss - often with the corrosion rate for
coupons showing 10% or less of the true wall loss occurring. Where questions
arise, independent testing in the form of a metallurgical analysis will confirm
the accuracy of ultrasonic testing over corrosion coupons in every
case.
Unfortunately, corrosion coupons
have been in service for so long that their function and accuracy are now
accepted without question; their results relied upon almost blindly. Very
obvious faults in their ability to report a corrosion rate relative to the
actual pipe, and clear examples where they have failed to return accurate data,
are typically ignored by even those relying upon such results as part of their
professional service. While the use of corrosion coupons present no threat in
monitoring a piping system that truly exists having a low corrosion rate, they
can have severe consequences to a building property that does have a high
corrosion problem, and is thereby misinformed - as CVI has proven time and
again.

Technically,
corrosion coupons very well estimate the potential for a chemical inhibitor to
protect a new steel or metal surface (or the potential for a liquid to corrode
a new metal surface). Most authorities recognize and admit that they do not
represent the actual wall loss at the pipe's interior. This is a significant
difference from the commonly applied definition of what is being measured and
reported by corrosion coupons, and often vastly different from what a client
understands the coupon based corrosion rate information means.
That a corrosion coupon
test result does not truly represent the corrosion rate at the pipe wall is
rarely expressed to a client who is employing coupons to guide them in
their chemical treatment application and corrosion management
needs.
In many cases we
have been involved, reported corrosion coupon rates are not even within the
realm of possibility. Some reflect numbers that would be even difficult to
reproduce in the laboratory under ideal conditions. Corrosion coupon rates
reported at 0.05 or 0.1 mils per year (MPY) for open condenser water systems
are commonly offered to clients as proof that the chemical water treatment is
performing, when such numbers are not even feasible, and should be immediately
suspect. Aside from the inherent inaccuracy of corrosion coupons to report
corrosion activity at the pipe surface, manipulation of the results and
outright fraud are also occasional elements
seen.
CVI has witnessed corrosion coupons
that have been coated with clear lacquer, sealants, and even nail polish. We
have seen corrosion coupon reports that have been tampered with to reflect low
corrosion rates where a higher rate was actually measured. Aside from offering
a check on the accuracy of a specific laboratory, the use of multiple corrosion
coupon testing labs is often for the purpose of eliminating any fraud in the
handling and reporting of the corrosion coupon
rate.
Corrosion coupons unfortunately do
not provide an accurate or realistic estimate of the actual corrosion activity
taking place at the surface of the pipe. As the corrosion rate of the piping
system itself increases, it is common to see an even greater difference between
coupon reported losses and actual pipe wall loss. The presence of even a
moderate amount of interior deposits will almost completely eliminate any
relevance between a coupon based corrosion rate and the wall loss which is
actually taking place at the pipe surface.
See Technical Bulletin
M-19 regarding the benefit and limitations of corrosion coupons.
Plus, basing an entire chemical program upon the results of corrosion coupons
taken at only one point in the system is risky in itself, given the low
probability that any one test area is representative of the entire piping
system.

A client manages
an 11 year old, 42 floor office building in a major U. S. city. Refrigeration
is provided by a 24/7 condenser water system running the entire height of the
building, with two individual package units on each floor serving A/C and
computer cooling needs. One 4 in. take-off from each 24 in. carbon steel riser
supplies water to and from the A/C units, while a second 2-1/2 in. set of
take-offs are available for future use, and valved off at most floors. Main
risers are standard grade ASTM A53 carbon steel of domestic manufacture and
having a specified wall thickness of 0.375
in.
The property management firm is
particularly recognized for very well maintaining its properties, and has a
chief engineer that places chemical water treatment as one of his highest
priorities. Chemical treatment is maintained by a nationally well known and
established chemical supplier, with no expense seemingly spared in installing a
fully automated chemical injection and bleed system. Annual costs for water
treatment chemicals and service alone exceed
$65,000.
On-site chemical testing is
performed twice per day and all necessary adjustments made to maintain the
chemical levels within design parameters. A representative of the chemical
company is on site once per month or more in order to discuss results and to
adjust the treatment schedule if necessary. Two independent and highly
respected water treatment consultants are employed to review all data, analyze
water samples, and make their own recommendations on a bimonthly basis. Added
expenses for the water treatment consultants approach the cost of the chemical
water treatment contract.
The building was
designed and built with an automatic full flow water filtration system capable
of reducing particulates down to 100 microns - a tremendous benefit, and one
not often seen specified today. In addition, they have installed a large sand
filter at the roof level MER to further remove the condenser water particulates
to below 1 micron. The water is clear and free of turbidity, and both filters
are said to work flawlessly.
Corrosion
activity within the condenser water system is monitored by one elaborate
corrosion coupon rack installed at the roof level MER. The coupon rack is
constructed of PVC, and offers multiple coupon ports. In addition to the
coupons installed by the chemical treatment contractor and changed on both 45
and 90 day intervals, two other sets of coupons are provided and analyzed by
both independent water treatment consultants. Three independent sets of
corrosion coupons thereby serve to define the effectiveness of the water
treatment program, and as the basis of the decision making at this large
building property.

While this
building property has always taken a proactive approach to the chemical water
treatment, certain signs are present to suggest a hidden corrosion problem.
Some connections at the isolation valves to various cooling units show
corrosion product at the threads. Pinholes in some of the smallest diameter
piping to supplemental tenant A/C cooling has required replacement. Random
copper cooling coils have failed due to pinholes. Blowing down any dead leg on
even a regular basis produces a high quantity of iron oxide before the water
finally runs clean. Rust and scale accumulates in the cooling tower pans
sufficiently to require periodic
removal.
The capture volume of the two
condenser water filters is unknown since it discharges directly to floor drains
rather than to a holding tank. The sand filter inlet line is oriented
perpendicular to the flow of water at the high velocity discharge of the
condenser water pumps - thereby reducing its effectiveness.
See Technical Bulletin
# W-3 regarding why many filtering systems fail to perform.

While there is
some suspicion by the engineering department that a corrosion problem may
exist, corrosion coupon results show no cause for concern. Estimated corrosion
rates of all three coupon laboratories agree to within 15% of each other, and
report consistently low corrosion rates of about 0.4 mils per year (MPY),
excellent by any standard.
Each set of
coupon results are reviewed and compared with prior results, minor changes in
treatment levels are recommended by the chemical treatment representative or
water treatment consultants, and minor changes made to the treatment program if
necessary. The independent water treatment consultants provide quarterly
reports generally supportive of the actions taken by the engineering staff. As
a result of the favorable corrosion coupon results, all parties concerned are
pleased at the results of their own efforts, and of each
other.
Lingering concerns due to the rust
deposits found within the system, however, prompt a further investigation into
the condition of the system using ultrasonic thickness (UT) testing - a testing
method never before employed at this building property.

CorrView
International, LLC initiates an investigation with the objective of providing
the most thorough piping evaluation possible within the one day of field
testing contracted. Ultrasonic testing is performed according to our standard
procedure, and addresses all major areas of the building including, tower area,
pump room, risers at various intermediate floors, threaded pipe, top and bottom
of the system, distribution lines to the A/C units, future taps at the risers,
and miscellaneous pipe fittings. Review our UT testing
and reporting specifications. A total of 40 individual piping
locations are evaluated as part of this
investigation.
Our ultrasonic testing
immediately identifies a high wall loss, and a wide 60-100 thousands variance
in the high to low wall thickness measurements, which is a strong indication of
a pitting condition. Significantly, it also identifies random high thickness
values suggesting that the pipe was received and installed above specification.
In fact, new pipe can be produced +/- 12.5 percent of its ASME factory
specification and still be suitable for service. In this case, the use of
standard 12 in. through 24 in. pipe having a specified wall thickness of 0.375
in. is found with random thickness values of 0.410 in. throughout most areas
tested. The pipe wall is therefore assumed to have been oversized by 10%, and
all calculations based upon this new higher starting wall thickness of 0.412
in.
While in one respect a clear benefit
to the building property by its heavier wall thickness, it has to be remembered
that any calculation of corrosion rate must then take into account the higher
wall loss from this higher assumed starting point - a common flaw in many
corrosion reports. References made in some prior consultant reports of pipe
service life mistakenly use the ASME factory specification thickness of 0.375
in. , when actually, the pipe originated much heavier and with a
correspondingly much greater wall loss. This error alone results in a much
lower than true corrosion rate estimate.


Over its 11 years
in service, our UT testing shows a consistent corrosion rate of between 6 and 9
mils per year, far above the 0.4 MPY estimate of corrosion coupons by a factor
of more than 15 times. At most locations, a high to low wall thickness spread
of up to 100 thousands or 0.100 in. exists - confirming a serious pitting
condition. No indication of pitting is shown in the corrosion coupon
results.
Given that a 5 MPY corrosion rate
at 24 in. pipe will produce an annual loss of approximately 121 lbs. of steel
pipe for every 100 linear feet, we can roughly estimate that far greater than
12,000 lbs. of original pipe wall has already been lost due to corrosion over
the life of this property thus far. Much of this rust volume is removed in
blowdown, cleanings, and through filtration, while some percentage will settle
and accumulate within the system itself. It is that remaining amount of
corrosion debris which will cause future problems.
See Technical Bulletin
C-1 regarding the volume of corrosion product created at different corrosion
rates.
The same high corrosion
rate is found throughout most areas tested, which helps to confirm the system
wide presence of whatever problem exists. Testing shows far less corrosion and
pitting at the vertical risers, and testing of any horizontal lines clearly
identifies much higher wall loss at the bottom and lower sides of the pipe -
further suggesting a deposit related corrosion problem. A slightly lower
corrosion rate is found at the smallest diameter piping. However, galvanic
activity is observed at some brass valves, which would further reduce wall
thickness at the threads, immeasurable through our UT testing methods, and
therefore remaining an unknown.
Schedule
40 pipe is identified as the material used in all small diameter threaded
applications, and all examples tested are documented to exist below minimum
acceptable wall thickness standards. See Technical Bulletin
# P-1 about the effect of wall loss in threaded applications. With a
beginning wall thickness of 0.154 in. for 2 in. schedule 40 black pipe, our
testing showed remaining thickness values of between 0.118 in. and 0.130 in. at
most examples. Having an initial thread loss of 0.085 in. which must be
deducted from its available wall, we can easily document that barely 0.033 in.
remains at certain areas of the threads, and that such small diameter threaded
pipe represents a high priority area for failure to occur.
Review our comparison
of pipe schedule and wall thickness values.
The larger 2-1/2 in. future take-off lines at
each floor show the same degree of corrosion as elsewhere, with slightly higher
wall loss at the threaded end - suggesting galvanic loss at the steel to brass
connection. Current wall thickness values of between 0.140 in. to 0165 in.
remain, but a higher thread loss of 0.115 in. exists for 2-1/2 in. and larger
pipe - thereby leaving little steel at the threads themselves. No galvanic
insulators are installed. See Technical Bulletin
P-10 regarding galvanic corrosion.
With corrosion and thread loss
considered, most of the future take-off lines tested are shown in highly
deteriorated condition and in need of replacement. Some current wall thickness
values of under 0.140 in. are found - meaning that only 0.025 in. remains at
some areas of the threads. Compounding the difficulty of replacing these two
sections of pipe at 42 different floor locations is the fact that the pipe is
directly welded to the riser, rather than being more appropriately threaded
into a threadolet fitting. Repair now requires burning off the existing pipe
and welding in a new fitting - an expensive and time consuming effort.

Our ultrasonic
testing report is clear in result and overwhelming in the evidence presented of
a system wide high corrosion and pitting problem.
Review a sample CVI
ultrasonic testing report. This information dramatically conflicts
with years of previously offered evidence of a low corrosion rate and no
problem concerns, yet coincides with physical observances about the
system.
As a result of favorable corrosion
coupon results, clearly evident problem signs such as leaking threads and
pinhole failures were explained away as isolated failures due to causes other
than a high corrosion rate. The accumulation of rust deposits in the tower pans
and drain down lines are also wrongly interpreted as the result of airborne
particulates being captured by the cooling tower, or other
causes.
With only one method of corrosion
monitoring provided to indicate corrosion control effectiveness relied upon for
its entire 11 years in service, this building property obviously existed under
a false sense of security for many years. Valuable time was lost where an
earlier identified corrosion problem might have been easily brought under
control. Whether the corrosion problem was greater initially and is now a
lesser problem, or whether the corrosion losses shown took place in more recent
years cannot be identified at this late stage of investigation. Undebatable,
however, is the finding that a significant amount of wall loss has taken place;
undetected and unreported through all previous monitoring and investigation
efforts.

Fundamentally,
the reliance on corrosion coupons as the exclusive test method is at fault. In
establishing a corrosion monitoring program, the only questions raised about
the corrosion coupons were of the accuracy of the various labs used, rather
than if the coupon test method was returning accurate and representative data.
Enormous effort was essentially wasted in cross checking test results from a
methodology not likely to provide a result representative of the true system
corrosion rate. All three labs provided accurate corrosion rate data from metal
coupon samples not representative of the actual pipe
loss.
It may have been reasonably assumed
that corrosion coupons in a new piping system would have provided accurate
corrosion loss estimates initially, but over time, such a relationship
diminishes. The observance of deposits in the tower pan and dead legs should
have suggested an interior deposit problem very likely to further limit the
accuracy of the coupons installed. It should have also immediately suggested
the need to establish alternative corrosion testing
methods.
The placement of the corrosion
coupon rack at only one location, at the roof area MER near the chemical feed
station, clearly plays a part in not being able to identify true corrosion
activity at the lowest points within the system, and elsewhere. Furthermore,
its construction of PVC plastic completely eliminates any electrical contact,
and therefore significantly minimizes what corrosion is essentially defined as
being - an "electro-chemical" reaction.
Significant other faults of corrosion
coupons exist which are well defined in previously referenced articles on this
Internet site. Suffice it to say that in their isolated state, unaffected by
particulates, rust deposits, flow rate, electrical currents, galvanic activity,
under deposit corrosion, microbiological growths, and the many other factors
which do exist within most typical condenser water systems, there is no other
reasonable expectation than for corrosion coupons to produce artificially low
corrosion rate results.
Ironically, the
failure of corrosion coupons to produce an accurate and representative
corrosion rate assessment in this case was quickly recognized and agreed to
exist by both the chemical treatment contractor and independent corrosion
consultants once evidence in our UT report was presented. In this case, as is
typical, blame was quickly focused by all upon the corrosion coupon testing
method.

Following
presentation of our ultrasonic pipe testing report, CorrView International, LLC
made certain recommendations in an attempt to help bring the corrosion rate
under control. Unfortunately, the advanced stage of corrosion, especially at
the smallest threaded fittings, makes mandatory certain difficult and extensive
repairs before any realistic effort to control the corrosion rate can be
considered.
In addition to our review and
explanation of our UT test results, CVI recommended the following actions:
- Replace all
small diameter threaded steel piping of 2-1/2 in. or less with new schedule 80
stock. Address the lowest floors first.
- Replace all
future take-off lines at the risers with new schedule 80 stock. Install welded
and flanged valves. Address the lowest floors
first.
- Remove
representative samples of smaller size pipe for metallurgical
analysis.
- Understand that
any under deposit corrosion condition will likely become more severe if not
corrected by removing the interior deposits first. Sufficient interior deposits
will effective eliminate any benefit of the chemical treatment
program.
- Discuss
chemical cleaning options with the chemical treatment provider. Use only mild
cleaners and avoid acids. Test any chemical cleaning agent for effectiveness
and safety against actual deposit laden piping from the system. Establish a
method for evaluating the progress of any cleanout
method.
- Install
multiple spool pieces in different areas of the building. Install new pipe for
the evaluation of the effectiveness of the chemical inhibitor. Install the old,
existing pipe for evaluation of any chemical cleanout
effort.
- Investigate
whether smaller filter elements can be installed at the full flow filters, and
whether a lower particle retention will reduce flow rate below acceptable
limits.
- Relocate the
suction inlet line for the sand filter to the very end of a straight line run,
rather than its point perpendicular to the water flow. Consider relocating the
sand filter to the very bottom of the system on the downward supply line.
Pressures at the base of the system may be too high for this unit
however.
- Install holding
tanks at the discharge of both filtering systems in order to judge their
effectiveness and degree of any corrosion problem.
- Install LPR or
linear Polarization Resistance corrosion measurement probes at various points
of the condenser water system in order to identify instant corrosion rate, and
quickly assess the effectiveness of any remediation
efforts.
- Require that
the water treatment provider and both water treatment consultants formulate a
new assessment of the condenser water system based upon updated corrosion rate
information, and provide recommendations to reduce the corrosion rate to below
1 MPY.
- Install UT test
templates at various areas of the pipe for the purpose of repeatedly returning
to the same area of pipe for more precise ultrasonic testing. This is the
ultimate corrosion monitoring method, which uses the pipe itself as a virtual
corrosion coupon.
- Install
CorrView corrosion monitoring plugs at various points of the condenser water
system in order to provide backup monitoring.
While significant
disadvantage exists at this later point to correct the existing corrosion
condition, three important steps need to be taken as soon as possible.
1. First is to establish a
corrosion monitoring procedure that is accurate in representing what is
actually taking place within the system and reliable over time. Establishing
multiple testing methods at various points within the system is strongly
recommended.
2. Second is to
identify and replace any vulnerable piping that is either near the point of
failure, or that might be pushed to failure through the application of any
chemical cleaning or corrective
measures.
3. Third is to identify,
test, and them employ a chemical cleaning program in order to remove the years
of accumulated iron oxide corrosion product. Only at that point can the current
corrosion and pitting rate be reduced.

The above case
history is an extremely common scenario we have seen to various extent in many
dozens of testing investigations. Typcially, a building property relies
exclusively upon the results of corrosion coupons, and then realizes they have
a severe corrosion problem years later. Finding someone to pin the blame on is
often the first reaction, with the plant engineer and/or water treatment
contractor often receiving the greatest criticism. Once recognized as a threat
to building operations, the appropriation of major funds is required to correct
the problem.
It is exactly this failure
of corrosion coupons to accurately represent true corrosion activity within
piping systems that the CorrView ® corrosion monitor was
developed.
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Copyright
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