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Open cooling
tower systems are well recognized as existing under much greater environmental
stresses, and therefore traditionally suffer a greater corrosion loss. Compared
to a closed chill water or secondary piping system which will typically show a
1-2 mil per year (MPY) or less corrosion rate, open systems generally range
from 3-5 MPY to well above. See our photo gallery
of various corrosion types.
In
addition to a difference in wall loss and corrosion rate, closed systems rarely
suffer the more severe corrosion attack caused by microbiologically influenced
corrosion (MIC), under deposit pitting, and galvanic corrosion at dissimilar
metals. While a severely corroded closed piping system may show a 5-8 MPY
corrosion rate, severe problems at an open water system can produce a corrosion
rate of 25-50 MPY, and more.

Clearly, many
forces are at work within different types of piping systems to create such
variances in corrosion rate. Some are well outside the control of any building
owner or plant operator, or of the chemical water treatment contractor whose
responsibility it is to provide adequate corrosion control.
Review a summary of
piping quality, operating, and design changes which have
occurred.
Viewing the operating
differences between both closed and open piping systems offers some basic
explanation of this variation in corrosion rate:
- The cooling
tower of an open piping system acts as a giant air filter and gas scrubber, and
operates under almost identical principals for pollution control units used for
industrial applications. Therefore, a substantial volume of airborne dirt and
particulates are captured and introduced into an open system, but not a closest
system.
- The greater
volume of dirt, iron oxide, and other particulates which are captured by open
systems then becomes the initiating cause for higher corrosion rates. This in
turn will often result in extremely damaging under deposit or cell corrosion
problems for cooling tower, process water, or other open piping systems. Such
externally introduced deposits are not a problem for closed
systems.
- Microbiological growths, while occasionally a problem in closed
systems, are a continuous threat to any open piping system due to abundant
oxygen, and a never ending supply of new food and microorganisms collected
through the effect of the water washing through the air.
- An open piping
system exposes its contents to some degree of sunlight for part of its cycle -
thereby providing needed energy to algae and other light dependant
microorganisms.
- Due to the
aerating action of the cooling tower, water in an open system is typically
oxygenated to its maximum limit - thereby providing abundant oxygen for
microbiological growths and metal oxidation.
- Condenser or
open water systems operate at higher temperatures by approximately 50-70 º
F. over a closed chill water system. Such higher temperatures are in the
optimal growth range for many microorganisms. Higher operating temperatures are
also recognized for increasing the corrosion rates in most operating
environments by speeding up the various chemical
processes.
- The biocides
prescribed for open water use carry with them relatively short half lives in
order that their discharge in the blowdown does not negatively affect the
bacterial cultures critical to the operation of local wastewater treatment
plants. Therefore, controlling microbiological growths becomes a much greater
problem for open systems due to both higher organic loading and restrictions on
the available countermeasures.
- The air
scrubbing action of the cooling tower absorbs many gaseous materials and
pollutants, often lowering pH significantly. Nutrients scrubbed from area
kitchen exhausts often fuel excess biological activity and MIC, while the
sulfur dioxide fume from a boiler or power plant exhaust can produce acidic pH
conditions of 6.0 or lower.
- Cooling tower
or open water systems require a percentage of their make-up water to be blown
down or discharged from the system in order that calcium carbonate, magnesium
carbonate, and other hardness components do not concentrate sufficiently to
produce high total dissolved solids (TDS) and a scaling condition. A constant
blowdown from the system, however, also means a substantial loss of both
corrosion inhibitor and microbiocide.

An obvious
question, therefore, becomes the inversely proportional degree of chemical
water treatment protection provided between open circulating systems, which
exist at such greater threat, and closed systems, which often present little if
any concern. And the answer lies in the last difference between such systems,
as cited above.
Typically, an open
condenser or process water system will be chemically treated at a concentration
of 8-10 PPM of molybdate, phosphonate, or some other rust inhibitor. Yet a
closed system may be maintained at 200 PPM or greater of the same product.
Notwithstanding the 20 to 1 or greater difference in chemical concentration for
a typical closed system, perhaps 80% or more of an annual water treatment
budget still pays for the chemical used at the open water side.

This is due to
the high volume of blowdown necessary for any open system - which is greatly
dependant upon the characteristics of the make-up water. Blowdown rates can
range from 5-10% of the make-up, to as much as 30% or more in hard water or
areas of high total dissolved solids (TDS). In moderately sized open water
systems, the chemical treatment of tens of thousands of gallons of water per
day may be required.
While the true
evaporation of water leaves any treatment chemicals behind, cooling tower
blowdown, and the loss of solid water droplets through the fan discharge, or by
wind drift and overspray requires adding chemical to maintain desired treatment
levels.
Considering for illustration a
typical evaporation rate based upon 30 gallons per minute per 1,000 tons of
refrigeration, we can then estimate that a 5,000 ton system will make-up
approximately 150 gallons per minute (GPM) or 216,000 gallons during a 24 hour
period. Assuming a high allowable cycles of concentration or low to moderate
blowdown rate of 10% then means the necessity to chemically treat a new 21,600
gallons of water every day, or 151,000 gallons per week. A 20% blowdown
requirement would double that
amount.
Alternate methods of calculating
cooling tower evaporation, as well as useful formulas for cycles of
concentration, blowdown and make-up are rate are provided in the below
table:

To determine daily
evaporation rate for process cooling systems |
|
Tower Recirculation Rate in GPM x
Average Temperature Drop in º F. x Hours of Operation Per Day x 0.06 =
Gallons Per Day (GPM) |
To determine daily
evaporation rate for HVAC cooling systems |
Condenser Water Recirculation Rate in
GPM x Average Temperature Condenser Water Drop in º F. x Load Factor in
Percent / 100 x Hours of Operation Per Day x 0.06 = Gallons Per Day
(GPD) |
To roughly estimate daily
evaporation rate for any circulating system |
Condenser Water Recirculation Rate in
GPM x Average Temperature Condenser water Drop in º F. x 0.0008 = Gallons
Per Day (GPD) |
To determine the
approximate rate of drift losses |
Condenser Water Recirculation Rate in
GPM x 0.0002 = Gallons Per Day (GPD) |
To determine cycles of
concentration |
Maximum Concentration of Chlorides /
Concentration of Chlorides in The Make-up Water |
To determine daily blowdown
rate |
Evaporation Rate - [(Cycles of
Concentration-1) x Drift Losses]) / (Cycles of
Concentration-1) |

Chemically
treating such a large volume of new make-up water at the higher 200-300 PPM
levels necessary to produce reliable 1 MPY corrosion control would require an
enormous expenditure given the high cost of today's corrosion inhibitors and
microbiocides - typically exceeding $1,000 per 55 gallon drum. Paying possibly
20 times the cost of an existing water treatment contract is virtually
prohibitive regardless of the expected benefit in extending system life.
For this reason primarily, lower chemical
concentrations are usually specified for open water systems. It is not because
of any lesser need or some scientific reasoning often suggested by water
treatment contractors - but simply because of the high costs involved.

With the
competitive nature of the chemical treatment business, cost always plays an
extremely important role. Likely set by the previous history of chemical
contracts, or by the budget demands of the client, water treatment specialists
often need to meet a pre-determined price range. The interests of one chemical
supplier to recommend and charge for higher and more appropriate inhibitor
levels, against others that would not, would guarantee business failure given
the tight and competitive market which
exists.
So in effect, the level of
chemical provided, and the degree of corrosion control produced, is not
entirely dependant upon the chemical supplier, the effectiveness of the
inhibitor chemicals, nor any other plant engineering actions - but by the
budget constraints of the client to some degree.
Through some reasoning, likely not well
defined or publicized, the higher corrosion rates produced at lesser inhibitor
levels have been judged as acceptable by both client and water treatment
contractor alike. It is simply a trade off between pipe service life, the
possibility of operating problems, and money.

In reality, most
large diameter piping systems will last their intended lifespan at those higher
3-5 MPY corrosion levels. However, such higher corrosion levels always present
greater opportunity for more severe operating problems to develop, and narrow
the margin of safety between trouble free operation and disaster.
Higher corrosion rates also lead to an
inevitable build-up of deposits and other secondary operating problems.
See Technical Bulletin
C-4 about the problems associated with interior
deposits.
For smaller diameter
piping, and especially where threaded schedule 40 pipe is involved, any higher
corrosion rate exceeding 1 MPY will inevitably shorten pipe life. The more
recent use of thinner schedule 20 and schedule 10 pipe in many applications
almost eliminates any margin of safety where corrosion is concerned - virtually
guaranteeing a failure unless extraordinary corrosion control exists.
©
Copyright
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