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In recent years,
CorrView International has performed numerous ultrasonic investigations of
either very old pipe installed in the early 1900's, or at properties where a
combination of old and new pipe exist. We have found our test results a
remarkable demonstration of how environmental concerns and government
restrictions, combined with less tolerant engineering practices and cost
cutting, have greatly reduced the life expectancy of most new piping
installations.

First and foremost is the obvious
superiority in quality and corrosion resistance of much older pre World War II
pipe to that manufactured today - whether foreign or domestic. Our ultrasonic
testing of steam systems from 1911 have shown a minimal loss of only perhaps
20% from the original wall thickness. Testing of some galvanized steel domestic
water risers from 1920 have documented little if any wall loss and no loss of
the zinc coating.
We have certified 80
year old steam condensate pipe, which traditionally suffers from the acidic
conditions of condensate requiring frequent replacement, as useful for another
50 years of service. CVI has documented condenser water systems from the early
1940's to corrode at well below 1 mil per year (MPY) and offer hundreds of
years of future service - even at building locations where chemical treatment
was poor or non-existent.

In contrast, we
find few new properties able to control corrosion to below 5 MPY today without
expending extraordinary cost, supplemental filtration, close monitoring, and
greater maintenance effort. Chemical treatment programs costing $10,000 only 15
years ago now reach almost 10 times that expense. Fully automatic chemical feed
and bleed systems are no longer a convenience, but mandatory.
Yet, most piping evaluations performed at
newer building or plant installations using ultrasonic and metallurgical
testing typically reveal corrosion rates in the 3 to 5 MPY range - with some
examples exceeding 15 to 20 MPY. Such high rates often exist even in cases
where the chemical water treatment has been extremely well maintained.
See Technical Bulletin
C-2 for recommendations on maintaining good corrosion control.
We have either directly seen or have been
advised of condenser water or process piping systems which have been entirely
replaced after only 10 years in service or less. We have also found large
diameter 8 in. and 12 in. main risers repaired throughout some facilities using
emergency pipe clamps.
The use of more
expensive copper in smaller diameter distribution HVAC piping and process loops
has become almost standard practice today in the effort to avoid the damaging
effects of corrosion against carbon steel. Larger diameter 8 in. and 12 in.
condenser water piping systems running the entire height of large commercial
office buildings have been entirely replaced using extra heavy copper and even
304 or 314 stainless steel - such extraordinary expense applied solely in the
effort to avoid the destructive effects of corrosion rarely seen decades
earlier.
Wrought iron ASTM A 72 pipe,
which is well recognized and documented to provide extremely long service life
due to its internal grain structure and inherently high corrosion resistance,
can be found at many older pre-1970 properties. However, it was removed from
U.S. production in 1968 and is no longer available.
In examples where we have investigated
building properties having both new carbon steel and older wrought iron pipe,
we have consistently provided remaining service life estimates in the hundreds
of years for the wrought iron, as opposed to a few decades or less for the
newly installed carbon steel. In many examples, we have found unpainted and
un-insulated wrought iron pipe surviving 50 or more years of outdoor weathering
with only a fine layer of surface rust and the original ASTM markings still
intact.
While foreign produced pipe from
Japan, Korea, Mexico, South America, and Eastern Europe has traditionally shown
the greatest susceptibility to corrosion, we have not found recently produced
American carbon steel pipe products of significantly higher quality in terms of
corrosion resistance.
Aside from the
obvious net effects of stringent U.S. environmental controls and government
over-regulation, and the competition of low cost foreign steel, we have not
been able to establish suitable explanation for the obvious difference in new
vs. old American pipe products. Other changing factors acting against steel
pipe produced today obviously exist.
For
those many reasons, CVI strongly recommends that higher corrosion rates should
be anticipated regardless of any corrosion control measures planned or
implemented. It should be noted that standardized corrosivity tests, laboratory
methods capable of measuring the susceptibility of a metal to a typical
corrosive environment and rating that metal according to an established
numerical standard, are available, and offer an excellent prediction or warning
of potential corrosion problems. Please contact CVI for
further information about this evaluation service.

As mentioned, in
response to such observed increases in corrosion, many property managers,
operating engineers, and plant managers have turned to the use of Type L copper
tubing (commonly called pipe) for all smaller diameter run-out distribution
lines, and in some cases even for the main risers. This, however, may only be a
short term solution to an often more complex corrosion condition, and in some
cases may actually complicate an existing corrosion problem with additional and
unseen threats.
Important to consider in
the substitution of copper pipe for carbon steel is the significant difference
in initial wall thickness. Standard Type L B 88 copper for 3 in. diameter pipe
has a standard wall thickness of only 0.090 in., whereas 3 in. A 53 schedule 40
carbon steel has a wall thickness of 0.216 in. Compared to steel pipe having a
stress efficiency (a strength rating, not pressure rating) of 15,000 lb./sq.
in., B 88 copper pipe only offers 6,000 lb./sq. in. - a physical decrease in
strength of 60%. Copper pipe has less than half the tensile strength of steel,
and quickly loses that strength at high temperatures.
It is generally recognized that the
minimum acceptable wall thickness for copper tubing, under any conditions, is
approximately 0.040 in. At higher pressures, this minimum value increases -
thereby allowing for less physical wall loss to occur before being judged as
unsuitable for further reliable service.
Copper pipe, since it exhibits far less
physical strength than steel, will fail sooner than steel at the same wall
thickness dimension and under the same internal pressure - making it obvious
that the greatest threat for any copper piping or components installed in a
high rise property exists at the higher operating pressures of the lower
floors. The joint filler and quality of workmanship is extremely critical for
copper installed pipe, and has been documented as the starting point of many
failures.

While the
corrosion rate against copper is commonly believed to exist below 0.5 MPY under
all conditions, CVI has repeatedly documented that the same corrosive
environment responsible for raising corrosion rates against carbon steel past
10 MPY, will greatly increase the copper corrosion rate above its normal value
as well.
In many of our previous
ultrasonic examinations of condenser water systems which have shown a high
corrosion rate against carbon steel, we have also measured elevated corrosion
attack against the copper pipe. In fact, it is not uncommon to identify
condenser water systems having both a high steel corrosion rate of 15 MPY and a
corrosion rate against copper at 5 MPY or more.
Having a 5 MPY copper corrosion rate
aggressively working against piping which may only have an available 30 mils to
40 mils (0.030 in. to 0.040 in.) of wall thickness over minimum acceptable
standards translates to a system which will reach those minimum standards in
only a few years. Copper therefore should not be relied upon or viewed as any
form of safe or corrosion immune alternative given conditions where a high
carbon steel corrosion rate has already been documented, or where a high copper
corrosion rate is suspected.

For older
pre-1970's building properties or plant operations, it is unlikely to find
anything but schedule 80 or extra heavy black pipe in use for cooling water,
steam, or steam condensate service. However, today, schedule 40 is the
standard. Contrasted to a 0.322 in. wall thickness for an 8 in. section of
schedule 40 pipe, schedule 80 provides a significantly greater 0.500 in. of
available steel; for larger diameter standard grade pipe of 0.375 in. wall
thickness, extra heavy again offers 0.500 in. thickness.
See Technical Bulletin
P-5 for the pipe sizes and schedules of different piping
materials.
With internal
operating pressures rarely a deciding factor on pipe selection within the
commercial building and process cooling market, the previous use of heavier
materials, we believe, has been more intended to counteract the known effects
of corrosion activity and thereby provide longer service life.
It is important to realize that decades
ago, design engineers for piping systems assumed a reasonable and readily
achieved 1 MPY corrosion rate over an intended life expectancy of about 65
years for the typical building property. Therefore, a theoretical 65 mil
corrosion rate or "corrosion factor" was typically applied in piping
calculations for open condenser water or process cooling applications. (A 25
MPY "corrosion factor" was applied to closed systems such as for chill
and how water heating.)
In other words,
consulting and mechanical engineers estimated a total loss of only 65 mils of
pipe over the assumed lifetime of a typical condenser water or open process
water system. Any additional pipe wall thickness exceeding the corrosion factor
and that needed to contain the internal pressure and stresses was simply extra
insurance against corrosion and future operating problems.
Today, it is not unusual to measure the
same loss of 65 mils after only 5 to 10 years of service, and sometimes in as
little as 2 years. But while corrosion activity has obviously increased, the
response to the greater loss of pipe has not been factored into the design and
planning of modern piping systems - leaving very little if any tolerance for a
system wide corrosion rate exceeding a few mils per year.
CorrView International has identified
many building properties constructed in the 1970's and earlier as benefitting
by such engineering decisions. In the many decades since their construction, we
have documented the heavier schedule 80 pipe to have worn down to approximately
schedule 40 today. Some older properties, due to the original use of better
quality schedule 80 steel, actually have heavier and longer lasting pipe than
their newly constructed neighbors. It is an amazing paradox that CVI has well
documented throughout many years of ultrasonic testing.

This change in
engineering design toward using thinner schedule 40 pipe, and sometimes
schedule 20 and schedule 10, is far more obvious and threatening for smaller
diameter threaded applications - where the additional loss of metal during the
threading process often reduces the life expectancy of open condenser water or
process water piping to a decade or less.
See Technical Bulletin
# P-1 about the effect of wall loss in threaded
applications.
Threading
typically reduces the available wall thickness by over 50% - leaving a 0.154
in. thick piece of 2 in. schedule 40 pipe, less its thread cut of 0.087 in.,
with a true available and working wall thickness of only 0.067 in. beginning at
day one. See our thread loss
table.
For piping systems
having a typical 5 MPY corrosion rate, total penetration of the threads will
occur within 13 years of installation. In reality, failure usually occurs years
earlier. In fact, the use of schedule 40 or standard grade pipe in threaded
open water condenser applications does not even meet minimum acceptable
engineering guidelines for piping systems, and will typically provide only
10-15 years of service life under good corrosion conditions. The failure of a
threaded schedule 40 piping system in under 5 years is not unusual, based upon
our experience.

A growing concern
is the recent increase in the use of Victaulic or clamped constructed schedule
10 pipe in fire sprinkler service and even for condenser or open water systems.
While providing adequate wall thickness initially, schedule 10 pipe has
approximately half of the thickness of schedule 40, leaving virtually no
tolerance for corrosion to occur.
Where
the pipe is filled and left stagnant over extended time, a small amount of
corrosion takes place, oxygen is depleted, and the corrosion process virtually
stops. However, where the system is frequently drained, or where service
extensions, leaks, or repairs bring in fresh water, corrosion rates can reach
the level of open water systems, and premature failure is inevitable. Combined
with the use of thin wall schedule 10 pipe, a fire sprinkler system having any
influx of fresh water is almost guaranteed to experience premature
failure.
For a section of 8 in. condenser
water pipe that would have provided an extra heavy wall thickness of 0.500 in.
for a 1950's property, or 0.322 in. at a facility constructed of schedule 40 in
1985, the frequently seen use of schedule 10 now provides only 0.188 in. of
available wall thickness under substantially higher corrosion conditions.
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Schedule 80 - 0.500
in. |
Schedule 40 - 0.322
in. |
Schedule 10 - 0.188
in. |
Advanced failures
are therefore quite frequent where schedule 10 is employed, and easy to
understand in viewing the above relative illustration of different pipe wall
thickness schedules for 8 in. pipe. View a more detailed
comparison of various wall thickness values for carbon steel
pipe.
CVI overwhelmingly
recommends using heavier schedule 80 steel pipe in all small diameter
applications calling for threaded joints. We also recommend using no thinner
than schedule 40 pipe for fire sprinkler or condenser water systems - whether
using threaded, welded, or Victaulic or grooved clamped construction.

For decades,
building and plant engineers relied solely upon the use of chromate based
chemical additives to provide the required corrosion protection of steel piping
systems. With even the most inferior application methods, often nothing more
than an unmeasured scoop of chromate powder dumped into the cooling tower sump
at irregular intervals, corrosion rates could often be maintained at or below 1
MPY.
Biological fouling was a rarely
encountered problem due to chromate's inherent toxicity. Such trouble free
operation ended, however, in the mid-1980's - with the prohibition of all
chromate use in open water circulating systems in the United
States.
Today, molybdate, phosphate, and
other U.S. EPA approved chemical inhibitors rarely equal the effectiveness of
past chromate treatments. Though offering impressive corrosion suppression in
bench test or laboratory settings, non-chromate programs rarely provide similar
results under real world conditions. They are documented as being substantially
ineffective in stagnant, low flow, or dead ended piping areas. During many
years of ultrasonic pipe testing, CVI has identified numerous examples where
the highest corrosion rates have been found exclusively at those areas having
the lowest flows.
Non-chromate treatments
offer no microbiological or fungal control - thereby placing increased emphasis
on the use of alternating biocide chemicals. Unfortunately, biocides themselves
have had their effective half-life reduced to about 6 hours by U.S. federal and
state environmental authorities. The result - a legal limit of the amount of
biocide one can apply over a given period of time, as well as a legal
limitation over its strength, effectiveness, and the time it will remain
active.
And yet, microbiological activity
has been identified as playing an much greater role in metal corrosion then
previously thought - MIC being the most serious piping threat known.
See Technical Bulletin
# C-5 for more about the threat of
MIC.
The alternative, oxidizing
biocides such as chlorine, bromine and ozone, all offer excellent
microbiological control at the trade off of increased corrosion and pitting.
The common overuse of oxidizing agents such as chlorine and bromine on a weekly
or daily basis have been known to produce severe pitting of steel and copper
pipe, and to quickly remove the galvanizing coating from cooling tower pan
surfaces.

Together, the
combination of all the above named factors has placed a higher priority on
corrosion control which did not exist 20 years ago, and which has raised the
issue of chemical treatment, and the monitoring over its effectiveness, to new
levels of importance within those involved in building and plant engineering,
maintenance, and operations.
Virtually
all advanced piping failures we have seen have been traced back to an
ineffective or lacking water treatment program at some point in the building's
history - most notably due to poor initial cleanout and start-up procedures.
Quite clearly, the first six months of operation are critical for any building
or plant facility.
To the inherent
limitations of the chemicals must be added the experience and reputation of the
water treatment professional. A lack of knowledge, experience, and
professionalism, or a primary interest for profits, can be equally as damaging
to a piping system as a lack of chemical protection entirely.
A less reputable water treatment company
may be discovered and replaced, but the effects of even six months of
sub-standard service can initiate a lifetime of corrosion troubles for a
building or plant operation. A further limitation may also be the budget
constraints of the property or plant itself, or the need to meet a contract
limit established by a previous water treatment
vendor.
Ultimately, some building property
owner or plant operator is faced with with not only the difficult task of
correcting or replacing a piping system, but perhaps the responsibility for the
actions or inactions of those years prior as well. Constant attention, and a
thorough and accurate corrosion monitoring program is therefore they key to
trouble free operation.
©
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