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There is a
general understanding by those working within the building operations, plant
engineering, and water treatment fields that drained carbon steel pipe will
corrode to a higher degree than pipe which is always filled with water. This
produces a tremendous vulnerability to the piping system, and one which is
typically hidden from view. See Technical Bulletin
C-3 regarding the increase in corrosion activity found at drained
piping.
While the actual degree
of wall loss for drained pipe is in most cases undefined and only speculated
upon, a presumption that it does exist often prompts preventative action. For
those responsible for the operation of building or plant properties in Northern
sub-freezing climates, freeze protection for less than 24/7 operations is
required - thereby introducing new corrosion concerns as well.

Such wall loss
varies greatly, and is, unfortunately, far from being predictable. Pipe which
is drained and left in a wet condition has been documented to corrode at as
much as 10 or more times the rate of pipe left filled with chemically untreated
water. Yet in some cases, roof level pipe which has been drained and left to
dry has exhibited only slightly greater corrosion and pitting activity -
reducing service life, but not significantly threatening building or plant
operations. In some instances, pipe left drained over decades of winter lay-up
will show only a moderate increase in corrosion and pitting activity. In
others, 15 years of winterization will produce sufficient damage to require
pipe replacement.
In fact, the actual
amount of wall loss at drained pipe will vary greatly depending upon many
different factors and physical conditions, and is still not well understood or
explained by most piping and corrosion authorities. Two similar properties
having similar condenser water systems and operating under similar drain down
conditions may show dramatically different pipe corrosion characteristics.
Therefore, in order to minimize this potential corrosion threat to the best
degree possible, some preventative action is always advised.
Various influences on the degree of
corrosion occurring in drained down piping are:
- Inherent
corrosion resistance of the pipe
- Length of
downtime
- Fluctuation in
water level inside the drained pipe
- Pipe or ambient
temperature
- Number of years
drained
- Chemical
inhibitor and inhibitor doseage level
- Preventative
actions taken
- Infiltration of
outside air
- Horizontal or
vertical orientation of the pipe
- Moisture
content within the piping
- Location top or
bottom of the piping system
- Length or
travel of the piping system

Recognizing the
probability of such high wall loss, most building and plant managers will take
some action to safeguard or at least retard the potential corrosion damage.
Most commonly, high doseages of the normal chemical inhibitor are applied to
the system immediately before drain down - the theory being that higher
chemical levels will coat the pipe to provide greater corrosion protection. A
maintained molybdate level of 10 PPM therefore may be boosted to 50 PPM or
higher in the hope of providing greater corrosion protection.
In reality, such effort is virtually
worthless. Even a molybdate inhibitor level of 50 PPM is far less than the 100
PPM or greater maintained in any closed system - capable of producing only 1
mil per year (MPY) corrosion rates under much more ideal conditions. Our
ultrasonic testing of condenser water systems which have carefully followed
such procedures have shown no benefit whatsoever, with virtually the same high
wall loss shown as exists at unprepared
piping.
A more effective method, sometimes
employed, is to insulate and heat trace the pipe, and then maintain the pipe
filled with chemically treated water - an expensive option for a seasonal
cooling system. Given that substantial pipe wall deterioration will exist
wherever the the water level ends, it becomes necessary to maintain the entire
piping system full back to the cooling tower, heat tracing it accordingly.
Otherwise, such action only accomplishes moving the point of pipe wall failure
to somewhere else.

Displacing the
air and oxygen by a blanket of nitrogen gas is one very effective method for
protecting carbon steel pipe, but one rarely used in building and plant
operations. Quickly drying the pipe to extremely low relative humidity, is
another option. A new class of highly effective chemicals called Vapor
Corrosion Inhibitors (VCI) offers probably the greatest protection at
reasonable expense and effort, and can provide almost total corrosion
protection. See Technical Bulletin
# C-9 for further information on VCI corrosion inhibitors.
Few other options exist. Without
utilizing nitrogen gas, VCI, drying the system completely, or some other proven
method of lay-up protection, any drained piping system can be expected to show
greatly accelerated deterioration over time.

The greatest
level of metal deterioration often exists at the interface between water and
air - where saturated moisture exists in an abundance of oxygen. For any vessel
where the level of water is raised and lowered, such effect is especially
pronounced. In a typical piping system, variations in temperature may expand
and contract the water and pipe to create a small washing effect over a
localized area to produce severe wall
loss.
This exact corrosion scenario is
commonly found by our ultrasonic testing of domestic cold water storage tanks
and especially at steam condensate tanks. Performing thousands of wall
thickness measurements along a defined X - Y grid allows us to produce a
virtual three dimensional image of the interior tank wall, and often provides
clear illustration of any weakness at the tank
surface.
In the below example showing the
left and right sides of a 22 year old, 3,000 gallon cold water make-up storage
tank, ultrasonic testing showed a very defined deterioration of wall thickness
along the entire length of the shell and heads. This area of deterioration
directly corresponded to the high and low limits of its fill valve, producing a
very localized 30% deep penetration that would ultimately remove it from
service.
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This same
corrosion effect was also shown at the front and rear heads, further confirming
this common problem.
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Pipe corrosion
problems are often complex conditions developing over many decades of service.
Identifying their severity and extent is rarely evident from observation, and
typically requires a moderate degree of investigation for even the most simple
corrosion forms.
Ultrasonic testing (UT)
provides a high level of information with no interference to operations, and at
very moderate cost. With sufficient test points taken in the appropriate areas,
and given proper analysis of the resulting data, UT can provide an extremely
clear and accurate evaluation of pipe condition which may have escaped
detection for decades. See Technical Bulletin
P-7 for more about the level of information provided by ultrasonic
testing.
The below seven sets
of data are taken directly from an investigation into a 55 year old piping
system at a New York City property. With a total replacement of the central
chiller plant and cooling tower planned, consulting engineers justifiably
raised concern for the original 28 story condenser water riser piping. Due to
its age, this pipe was expected to have been extra heavy originally, and
assuming a moderate corrosion rate based upon its prior history of being well
maintenaned, was anticipated to fall somewhere at or below the ASME
specification for standard pipe, which has been often seen in other similar
properties. No operating problems or leaks had been
reported.
This 18 in. condenser water
piping system was constructed of extra heavy ASME A72 wrought iron pipe having
an original wall thickness of 0.510 in. Installed in 1949, the pipe had been
annually drained 1-3 floors inside the riser shaft every winter for freeze
protection between the months of November and
March.
Initial testing, beginning at the
lower floors, showed excellent result, with the wall thickness approaching that
of new extra heavy pipe in areas, and still far exceeding specifications for
new standard pipe - which was planned should the pipe require replacement.
Further testing, however, showed significant difference. As the various sets of
graphs and statistics show below, this piping system suffered greatly varying
wall loss depending upon the location of the pipe.







As a result of
this ultrasonic investigation, which due to its convenience and mobility
allowed testing in areas possibly overlooked otherwise, a very severe
deficiency at the top 5-6 floors of riser piping was detected. Initially
unexplained, the far lower wall thickness at the lower floors of the supply
riser only was identified as due to a constant leak all winter at the pump
packing glands. This constant leak would drain down the supply side pipe
through the pump, which due to its check valve at the discharge back to the
roof, prevented the loss of water from the return side riser
piping.
Our ultrasonic testing well
documented a very common problem for northern climates which drain their
cooling tower piping for freeze protection. It also showed that overlooked
events as simple as a minor leak at a pump seal can produce enormous
consequences given sufficient time.
In
this investigation, we initially determined the top 5-6 floors of piping in
need of replacement due to the effects of draining down. Such losses were
expected to cease at the point at which water level would be held full, as
evidenced by the results from the return riser piping. However, the totally
unexpected consequence of slowly draining down the supply side piping, and
exposing its entire length to the effects of drain down produced a lesser but
still significant wall loss - raising the question of whether any of the
original condenser water pipe would be suitable for future service.
©
Copyright
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